TY - JOUR
T1 - Silica bound co-pillar[4+1]arene as a novel supramolecular stationary phase
AU - Mekapothula, Subbareddy
AU - Addicoat, Matthew
AU - Boocock, David
AU - Wallis, John
AU - Cragg, Peter
AU - Cave, Gareth W.V.
PY - 2020/1/8
Y1 - 2020/1/8
N2 - A novel co-pillar[4+1]arene incorporating two bromo-octyl substituents has been synthesised for the first time, using microwave irradiation in high yield (88%) in under four minutes, and bound to the surface of chromatographic silica particles. The resulting new stationary phase has been successfully utilised to separate xylene isomers via liquid chromatographic techniques.
AB - A novel co-pillar[4+1]arene incorporating two bromo-octyl substituents has been synthesised for the first time, using microwave irradiation in high yield (88%) in under four minutes, and bound to the surface of chromatographic silica particles. The resulting new stationary phase has been successfully utilised to separate xylene isomers via liquid chromatographic techniques.
UR - http://www.scopus.com/inward/record.url?scp=85079247208&partnerID=8YFLogxK
U2 - 10.1039/c9cc09656f
DO - 10.1039/c9cc09656f
M3 - Article
VL - 56
SP - 1792
EP - 1794
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 12
ER -
