Silica bound co-pillar[4+1]arene as a novel supramolecular stationary phase

Subbareddy Mekapothula; Matthew Addicoat; David Boocock; John Wallis; Peter Cragg; Gareth W.V. Cave

doi:10.1039/c9cc09656f

Silica bound co-pillar[4+1]arene as a novel supramolecular stationary phase

Subbareddy Mekapothula, Matthew Addicoat, David Boocock, John Wallis, Peter Cragg, Gareth W.V. Cave

Research output: Contribution to journal › Article › peer-review

Abstract

A novel co-pillar[4+1]arene incorporating two bromo-octyl substituents has been synthesised for the first time, using microwave irradiation in high yield (88%) in under four minutes, and bound to the surface of chromatographic silica particles. The resulting new stationary phase has been successfully utilised to separate xylene isomers via liquid chromatographic techniques.

Original language	English
Pages (from-to)	1792-1794
Number of pages	3
Journal	Chemical Communications
Volume	56
Issue number	12
DOIs	https://doi.org/10.1039/c9cc09656f
Publication status	Published - 8 Jan 2020

Access to Document

10.1039/c9cc09656f

Silica bound co-pillar[4+1]arene as a novel supramolecular stationary phaseAccepted author manuscript, 532 KB

Cite this

@article{da833ea849984be28c77e1465caa56ab,

title = "Silica bound co-pillar[4+1]arene as a novel supramolecular stationary phase",

abstract = "A novel co-pillar[4+1]arene incorporating two bromo-octyl substituents has been synthesised for the first time, using microwave irradiation in high yield (88%) in under four minutes, and bound to the surface of chromatographic silica particles. The resulting new stationary phase has been successfully utilised to separate xylene isomers via liquid chromatographic techniques.",

author = "Subbareddy Mekapothula and Matthew Addicoat and David Boocock and John Wallis and Peter Cragg and Cave, {Gareth W.V.}",

year = "2020",

month = jan,

day = "8",

doi = "10.1039/c9cc09656f",

language = "English",

volume = "56",

pages = "1792--1794",

journal = "Chemical Communications",

issn = "1359-7345",

number = "12",

}

TY - JOUR

T1 - Silica bound co-pillar[4+1]arene as a novel supramolecular stationary phase

AU - Mekapothula, Subbareddy

AU - Addicoat, Matthew

AU - Boocock, David

AU - Wallis, John

AU - Cragg, Peter

AU - Cave, Gareth W.V.

PY - 2020/1/8

Y1 - 2020/1/8

N2 - A novel co-pillar[4+1]arene incorporating two bromo-octyl substituents has been synthesised for the first time, using microwave irradiation in high yield (88%) in under four minutes, and bound to the surface of chromatographic silica particles. The resulting new stationary phase has been successfully utilised to separate xylene isomers via liquid chromatographic techniques.

AB - A novel co-pillar[4+1]arene incorporating two bromo-octyl substituents has been synthesised for the first time, using microwave irradiation in high yield (88%) in under four minutes, and bound to the surface of chromatographic silica particles. The resulting new stationary phase has been successfully utilised to separate xylene isomers via liquid chromatographic techniques.

UR - http://www.scopus.com/inward/record.url?scp=85079247208&partnerID=8YFLogxK

U2 - 10.1039/c9cc09656f

DO - 10.1039/c9cc09656f

M3 - Article

SN - 1359-7345

VL - 56

SP - 1792

EP - 1794

JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

Silica bound co-pillar[4+1]arene as a novel supramolecular stationary phase

Abstract

Access to Document

Other files and links

Fingerprint

Peter Cragg

Cite this

Silica bound co-pillar[4+1]arene as a novel supramolecular stationary phase

Abstract

Access to Document

Other files and links

Fingerprint

Profiles

Peter Cragg

Cite this