Scale inhibitor core floods in carbonate cores: chemical interactions and modelling

Salima Baraka-Lokmane, K. Sorbie

Research output: Chapter in Book/Conference proceeding with ISSN or ISBNConference contribution with ISSN or ISBN

Abstract

In previous work (SPE 87447), the effect of pH on phosphonate/carbonate interaction was studied by performing variable pH core floods in short outcrop carbonate cores. Effluent concentrations of scale inhibitor (DETPMP), lithium tracer, calcium and magnesium were measured, as were the corresponding pH profiles. Such detailed sets of measurements are required to interpret the inhibitor/carbonate interaction mechanisms. This previous study showed that carbonate dissolution was evident in all core floods and on how this depended on pH. It also indicated where simple adsorption isotherms could describe this accurately and where this was not the case. Recently, we have performed additional core floods using carbonate core from a second block of this outcrop chalk using DETPMP scale inhibitor slugs at various concentrations and pH values. These results significantly extend previous work and are presented under the following two headings: Scale inhibitor/carbonate/pH interactions in short cores + modelling: Simple flooding cycles are described on the propagation of (Li traced) slugs of pH 6, 4, and 2 (no scale inhibitor) travelling through the carbonate core in order to study the behaviour of calcium, magnesium and effluent pH for various injected brine pH conditions. These results have been modelled and explained using the MultiScale software. “Contained” scale inhibitor floods in long (12”) carbonate cores: Contrasting floods using long (12”) carbonate cores have been performed where <1 PV of DETPMP is injected at the inlet and then back produced. In these floods, the core is never fully saturated and these floods are referred to as “contained” core floods [1]. Very extensive data on SI, cation (Ca, Mg and Li) and pH effluents are collected. These observations lead us to a number of conclusions on the factors that must be included in a full carbonate model. In particular, our experimental results – along with some simple modeling – greatly clarify the role of both calcium and magnesium in the mechanism SI retention in carbonate systems.
Original languageEnglish
Title of host publicationSPE100515. SPE Sixth International Symposium on Oilfield Scale
Publication statusPublished - 31 May 2006
EventSPE100515. SPE Sixth International Symposium on Oilfield Scale -
Duration: 31 May 2006 → …

Conference

ConferenceSPE100515. SPE Sixth International Symposium on Oilfield Scale
Period31/05/06 → …

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inhibitor
carbonate
modeling
magnesium
calcium
slug
effluent
outcrop
chemical
carbonate system
chalk
lithium
brine
isotherm
flooding
cation
tracer
dissolution
adsorption
software

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Baraka-Lokmane, S., & Sorbie, K. (2006). Scale inhibitor core floods in carbonate cores: chemical interactions and modelling. In SPE100515. SPE Sixth International Symposium on Oilfield Scale
Baraka-Lokmane, Salima ; Sorbie, K. / Scale inhibitor core floods in carbonate cores: chemical interactions and modelling. SPE100515. SPE Sixth International Symposium on Oilfield Scale. 2006.
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Baraka-Lokmane, S & Sorbie, K 2006, Scale inhibitor core floods in carbonate cores: chemical interactions and modelling. in SPE100515. SPE Sixth International Symposium on Oilfield Scale. SPE100515. SPE Sixth International Symposium on Oilfield Scale, 31/05/06.

Scale inhibitor core floods in carbonate cores: chemical interactions and modelling. / Baraka-Lokmane, Salima; Sorbie, K.

SPE100515. SPE Sixth International Symposium on Oilfield Scale. 2006.

Research output: Chapter in Book/Conference proceeding with ISSN or ISBNConference contribution with ISSN or ISBN

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AB - In previous work (SPE 87447), the effect of pH on phosphonate/carbonate interaction was studied by performing variable pH core floods in short outcrop carbonate cores. Effluent concentrations of scale inhibitor (DETPMP), lithium tracer, calcium and magnesium were measured, as were the corresponding pH profiles. Such detailed sets of measurements are required to interpret the inhibitor/carbonate interaction mechanisms. This previous study showed that carbonate dissolution was evident in all core floods and on how this depended on pH. It also indicated where simple adsorption isotherms could describe this accurately and where this was not the case. Recently, we have performed additional core floods using carbonate core from a second block of this outcrop chalk using DETPMP scale inhibitor slugs at various concentrations and pH values. These results significantly extend previous work and are presented under the following two headings: Scale inhibitor/carbonate/pH interactions in short cores + modelling: Simple flooding cycles are described on the propagation of (Li traced) slugs of pH 6, 4, and 2 (no scale inhibitor) travelling through the carbonate core in order to study the behaviour of calcium, magnesium and effluent pH for various injected brine pH conditions. These results have been modelled and explained using the MultiScale software. “Contained” scale inhibitor floods in long (12”) carbonate cores: Contrasting floods using long (12”) carbonate cores have been performed where <1 PV of DETPMP is injected at the inlet and then back produced. In these floods, the core is never fully saturated and these floods are referred to as “contained” core floods [1]. Very extensive data on SI, cation (Ca, Mg and Li) and pH effluents are collected. These observations lead us to a number of conclusions on the factors that must be included in a full carbonate model. In particular, our experimental results – along with some simple modeling – greatly clarify the role of both calcium and magnesium in the mechanism SI retention in carbonate systems.

M3 - Conference contribution with ISSN or ISBN

BT - SPE100515. SPE Sixth International Symposium on Oilfield Scale

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Baraka-Lokmane S, Sorbie K. Scale inhibitor core floods in carbonate cores: chemical interactions and modelling. In SPE100515. SPE Sixth International Symposium on Oilfield Scale. 2006