Geomorphic and hydrological controls on groundwater dolocrete formation in the semi‐arid Hamersley Basin, northwest Australia

Caroline Mather, David Nash, Grzegorz Skrzypek, Shawan Dogramaci, Pauline Grierson

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Groundwater dolocretes may exert an important geomorphic control on landscape evolution within sub‐humid to arid regions. However, the geomorphic and hydrogeological settings of dolocrete remain poorly described. The hydrochemical conditions of dolomite precipitation in groundwater environments are also not well known. Classic models of dolocrete formation explain dolomite precipitation from highly evolved groundwaters at the terminus of major drainage but do not explain dolocrete distributed in regionally elevated landscapes, upgradient of major drainage. This study investigated the mineralogy, micromorphology and stable carbon and oxygen isotope compositions of three dolocrete profiles within a regionally elevated sub‐basin of the Hamersley Ranges in the Pilbara region of northwest Australia. We sought to establish the environmental and hydrochemical conditions and present a model for dolocrete formation. We found that dolocrete formed within zones of emerging groundwater under saline‐evaporitic conditions within internally draining sub‐basins, most likely during the Late Miocene and Pliocene. Saline‐evaporitic conditions were indicated by: i) the mineralogy, dominated by dolomite, palygorskite and smectite; ii) desiccation features and the presence of phreatic and vadose cements, indicative of a shallow fluctuating water table, and; iii) dolomite δ18O values (median = ‐5.88‰). Dolomite precipitation was promoted by evaporation and CO2 degassing from shallow Mg‐rich groundwater. These factors appear to have been the major drivers of dolocrete development without a requirement for significant down‐dip hydrochemical modification. Primary dolomite precipitation was possible due to the presence of microbial extracellular polymeric substances (EPS). EPS provided negatively charged nucleation sites, which bound Mg2+, overcoming kinetic effects. High microbial activity within groundwater systems suggest these processes may be important for dolocrete formation worldwide and that groundwater dolocretes may be more pervasive in landscapes than currently recognised.
Original languageEnglish
JournalEarth Surface Processes and Landforms
DOIs
Publication statusPublished - 20 Jul 2019

Fingerprint

dolomite
groundwater
basin
driver
mineralogy
water
drainage
present
palygorskite
micromorphology
landscape evolution
degassing
Values
arid region
desiccation
smectite
nucleation
microbial activity
carbon isotope
oxygen isotope

Bibliographical note

This is the peer reviewed version of the following article: Mather, C. C., Nash, D. J., Skrzypek, G., Dogramaci, S., and Grierson, P. F. (2019) Geomorphic and hydrological controls on groundwater dolocrete formation in the semi‐arid Hamersley Basin, northwest Australia. Earth Surf. Process. Landforms, which has been published in final form at https://doi.org/10.1002/esp.4704. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.

Keywords

  • chemical sediments
  • dolomite
  • landform evolution
  • microbial EPS
  • stable isotopes

Cite this

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abstract = "Groundwater dolocretes may exert an important geomorphic control on landscape evolution within sub‐humid to arid regions. However, the geomorphic and hydrogeological settings of dolocrete remain poorly described. The hydrochemical conditions of dolomite precipitation in groundwater environments are also not well known. Classic models of dolocrete formation explain dolomite precipitation from highly evolved groundwaters at the terminus of major drainage but do not explain dolocrete distributed in regionally elevated landscapes, upgradient of major drainage. This study investigated the mineralogy, micromorphology and stable carbon and oxygen isotope compositions of three dolocrete profiles within a regionally elevated sub‐basin of the Hamersley Ranges in the Pilbara region of northwest Australia. We sought to establish the environmental and hydrochemical conditions and present a model for dolocrete formation. We found that dolocrete formed within zones of emerging groundwater under saline‐evaporitic conditions within internally draining sub‐basins, most likely during the Late Miocene and Pliocene. Saline‐evaporitic conditions were indicated by: i) the mineralogy, dominated by dolomite, palygorskite and smectite; ii) desiccation features and the presence of phreatic and vadose cements, indicative of a shallow fluctuating water table, and; iii) dolomite δ18O values (median = ‐5.88‰). Dolomite precipitation was promoted by evaporation and CO2 degassing from shallow Mg‐rich groundwater. These factors appear to have been the major drivers of dolocrete development without a requirement for significant down‐dip hydrochemical modification. Primary dolomite precipitation was possible due to the presence of microbial extracellular polymeric substances (EPS). EPS provided negatively charged nucleation sites, which bound Mg2+, overcoming kinetic effects. High microbial activity within groundwater systems suggest these processes may be important for dolocrete formation worldwide and that groundwater dolocretes may be more pervasive in landscapes than currently recognised.",
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Geomorphic and hydrological controls on groundwater dolocrete formation in the semi‐arid Hamersley Basin, northwest Australia. / Mather, Caroline; Nash, David; Skrzypek, Grzegorz; Dogramaci, Shawan; Grierson, Pauline.

In: Earth Surface Processes and Landforms, 20.07.2019.

Research output: Contribution to journalArticleResearchpeer-review

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AB - Groundwater dolocretes may exert an important geomorphic control on landscape evolution within sub‐humid to arid regions. However, the geomorphic and hydrogeological settings of dolocrete remain poorly described. The hydrochemical conditions of dolomite precipitation in groundwater environments are also not well known. Classic models of dolocrete formation explain dolomite precipitation from highly evolved groundwaters at the terminus of major drainage but do not explain dolocrete distributed in regionally elevated landscapes, upgradient of major drainage. This study investigated the mineralogy, micromorphology and stable carbon and oxygen isotope compositions of three dolocrete profiles within a regionally elevated sub‐basin of the Hamersley Ranges in the Pilbara region of northwest Australia. We sought to establish the environmental and hydrochemical conditions and present a model for dolocrete formation. We found that dolocrete formed within zones of emerging groundwater under saline‐evaporitic conditions within internally draining sub‐basins, most likely during the Late Miocene and Pliocene. Saline‐evaporitic conditions were indicated by: i) the mineralogy, dominated by dolomite, palygorskite and smectite; ii) desiccation features and the presence of phreatic and vadose cements, indicative of a shallow fluctuating water table, and; iii) dolomite δ18O values (median = ‐5.88‰). Dolomite precipitation was promoted by evaporation and CO2 degassing from shallow Mg‐rich groundwater. These factors appear to have been the major drivers of dolocrete development without a requirement for significant down‐dip hydrochemical modification. Primary dolomite precipitation was possible due to the presence of microbial extracellular polymeric substances (EPS). EPS provided negatively charged nucleation sites, which bound Mg2+, overcoming kinetic effects. High microbial activity within groundwater systems suggest these processes may be important for dolocrete formation worldwide and that groundwater dolocretes may be more pervasive in landscapes than currently recognised.

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