Synthesis of the polymerizable room temperature ionic liquid AMPS – TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide

Tingting Weng; Guo Jianwei; L. Xinming; C. Yingde; Yang Xuejiao; Kun Zhang; Buning Zhang; Guoqiang Yin; Sergey Mikhalovsky; Lyuba Mikhalovska; Irina Savina; Carol Howell; Susan Sandeman

doi:10.1080/15685551.2013.840480

Synthesis of the polymerizable room temperature ionic liquid AMPS – TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide

Tingting Weng, Guo Jianwei, L. Xinming, C. Yingde, Yang Xuejiao, Kun Zhang, Buning Zhang, Guoqiang Yin, Sergey Mikhalovsky, Lyuba Mikhalovska, Irina Savina, Carol Howell, Susan Sandeman

Research output: Contribution to journal › Article › peer-review

Abstract

A polymerizable room temperature ionic liquid (RTIL), 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) - triethylamine (TEA), was synthesized by neutralization of AMPS with TEA in acetone followed by evaporation of the solvent under a reduced pressure at room temperature. The RTIL was characterized with fourier transform infrared spectroscopy, differential scanning calorimetry (DSC), and 1H NMR. Co-polymeric gels of the RTIL with acrylamide (AAm) were prepared by aqueous solution polymerization using N,N′-methylenebisacrylamide as a crosslinker, and ammonium persulfate as an initiator. Superabsorbency of the gels in aqueous and a series of organic liquids was investigated gravimetrically. DSC data showed that the glass transition temperature of AMPS - TEA was 59.4 °C. Poly (AMPS - TEA-co-AAm) gels exhibited superabsorbency in both water and a series of organic solvents. The mechanism for swelling in aqueous and organic media of the gels was critically discussed.

Original language	English
Pages (from-to)	140-146
Number of pages	7
Journal	Designed Monomers and Polymers
Volume	17
Issue number	2
DOIs	https://doi.org/10.1080/15685551.2013.840480
Publication status	Published - 17 Feb 2014

Keywords

2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS)
triethylamine (TEA)
room temperature ionic liquid (RTIL)
acrylamide
superabsorbency

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10.1080/15685551.2013.840480Licence: Unspecified

Susan Sandeman
- S.Sandemanbrighton.acuk
- School of Applied Sciences - Professor of Biomaterials and Tissue Eng.
- Applied Chemical Sciences Research Excellence Group
- Centre for Lifelong Health
- Centre for Regenerative Medicine and Devices
Person: Academic
Irina Savina
- I.N.Savinabrighton.acuk
Person: Academic

Cite this

Weng, T., Jianwei, G., Xinming, L., Yingde, C., Xuejiao, Y., Zhang, K., Zhang, B., Yin, G., Mikhalovsky, S., Mikhalovska, L., Savina, I., Howell, C., & Sandeman, S. (2014). Synthesis of the polymerizable room temperature ionic liquid AMPS – TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide. Designed Monomers and Polymers, 17(2), 140-146. https://doi.org/10.1080/15685551.2013.840480

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title = "Synthesis of the polymerizable room temperature ionic liquid AMPS – TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide",

abstract = "A polymerizable room temperature ionic liquid (RTIL), 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) - triethylamine (TEA), was synthesized by neutralization of AMPS with TEA in acetone followed by evaporation of the solvent under a reduced pressure at room temperature. The RTIL was characterized with fourier transform infrared spectroscopy, differential scanning calorimetry (DSC), and 1H NMR. Co-polymeric gels of the RTIL with acrylamide (AAm) were prepared by aqueous solution polymerization using N,N′-methylenebisacrylamide as a crosslinker, and ammonium persulfate as an initiator. Superabsorbency of the gels in aqueous and a series of organic liquids was investigated gravimetrically. DSC data showed that the glass transition temperature of AMPS - TEA was 59.4 °C. Poly (AMPS - TEA-co-AAm) gels exhibited superabsorbency in both water and a series of organic solvents. The mechanism for swelling in aqueous and organic media of the gels was critically discussed.",

keywords = "2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS), triethylamine (TEA), room temperature ionic liquid (RTIL), acrylamide, superabsorbency",

author = "Tingting Weng and Guo Jianwei and L. Xinming and C. Yingde and Yang Xuejiao and Kun Zhang and Buning Zhang and Guoqiang Yin and Sergey Mikhalovsky and Lyuba Mikhalovska and Irina Savina and Carol Howell and Susan Sandeman",

year = "2014",

month = feb,

day = "17",

doi = "10.1080/15685551.2013.840480",

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journal = "Designed Monomers and Polymers",

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Weng, T, Jianwei, G, Xinming, L, Yingde, C, Xuejiao, Y, Zhang, K, Zhang, B, Yin, G, Mikhalovsky, S, Mikhalovska, L, Savina, I, Howell, C & Sandeman, S 2014, 'Synthesis of the polymerizable room temperature ionic liquid AMPS – TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide', Designed Monomers and Polymers, vol. 17, no. 2, pp. 140-146. https://doi.org/10.1080/15685551.2013.840480

TY - JOUR

T1 - Synthesis of the polymerizable room temperature ionic liquid AMPS – TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide

AU - Weng, Tingting

AU - Jianwei, Guo

AU - Xinming, L.

AU - Yingde, C.

AU - Xuejiao, Yang

AU - Zhang, Kun

AU - Zhang, Buning

AU - Yin, Guoqiang

AU - Mikhalovsky, Sergey

AU - Mikhalovska, Lyuba

AU - Savina, Irina

AU - Howell, Carol

AU - Sandeman, Susan

PY - 2014/2/17

Y1 - 2014/2/17

N2 - A polymerizable room temperature ionic liquid (RTIL), 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) - triethylamine (TEA), was synthesized by neutralization of AMPS with TEA in acetone followed by evaporation of the solvent under a reduced pressure at room temperature. The RTIL was characterized with fourier transform infrared spectroscopy, differential scanning calorimetry (DSC), and 1H NMR. Co-polymeric gels of the RTIL with acrylamide (AAm) were prepared by aqueous solution polymerization using N,N′-methylenebisacrylamide as a crosslinker, and ammonium persulfate as an initiator. Superabsorbency of the gels in aqueous and a series of organic liquids was investigated gravimetrically. DSC data showed that the glass transition temperature of AMPS - TEA was 59.4 °C. Poly (AMPS - TEA-co-AAm) gels exhibited superabsorbency in both water and a series of organic solvents. The mechanism for swelling in aqueous and organic media of the gels was critically discussed.

AB - A polymerizable room temperature ionic liquid (RTIL), 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) - triethylamine (TEA), was synthesized by neutralization of AMPS with TEA in acetone followed by evaporation of the solvent under a reduced pressure at room temperature. The RTIL was characterized with fourier transform infrared spectroscopy, differential scanning calorimetry (DSC), and 1H NMR. Co-polymeric gels of the RTIL with acrylamide (AAm) were prepared by aqueous solution polymerization using N,N′-methylenebisacrylamide as a crosslinker, and ammonium persulfate as an initiator. Superabsorbency of the gels in aqueous and a series of organic liquids was investigated gravimetrically. DSC data showed that the glass transition temperature of AMPS - TEA was 59.4 °C. Poly (AMPS - TEA-co-AAm) gels exhibited superabsorbency in both water and a series of organic solvents. The mechanism for swelling in aqueous and organic media of the gels was critically discussed.

KW - 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS)

KW - triethylamine (TEA)

KW - room temperature ionic liquid (RTIL)

KW - acrylamide

KW - superabsorbency

U2 - 10.1080/15685551.2013.840480

DO - 10.1080/15685551.2013.840480

M3 - Article

SN - 1385-772X

VL - 17

SP - 140

EP - 146

JO - Designed Monomers and Polymers

JF - Designed Monomers and Polymers

IS - 2

ER -

Synthesis of the polymerizable room temperature ionic liquid AMPS – TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide

Abstract

Keywords

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Susan Sandeman

Irina Savina

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