Synthesis and applications of co-pillar[5]arene dithiols

Raghu R. Kothur, F. Fucassi, Gennaro Dichello, Ludovic Doudet, Wafa Abdalaziz, Bhavik Patel, Gareth W.V. Cave, Ian A. Gass, Dipak Sarker, Sergey Mikhalovsky, Peter Cragg

Research output: Contribution to journalArticle

Abstract

A novel copillar[4+1]arene incorporating alkylthiol substituents was synthesised in three steps and structurally characterised as the first example of a pillar[n]arene to incorporate two terminal thiols on the same aromatic ring. The macrocycle was attached to gold electrodes through a standard dipping technique. Cyclic voltammetry demonstrated selectivity for Li+over other alkali metal cations. The copillar[4+1]arene was also used as a capping agent in the preparation of 3nm gold nanoparticles.
Original languageEnglish
Pages (from-to)436-443
Number of pages8
JournalSupramolecular Chemistry
Volume28
Issue number5-6
DOIs
Publication statusPublished - 24 Nov 2015

Keywords

  • Pillar[5]arenes
  • macrocycles
  • gold nanoparticles
  • surface modification

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  • Activities

    • 1 Research degree
    • 1 Invited talk

    Masters Degree by Research (France) - Mr Victor Jasny (University of Tours at Blois)

    Dipak Sarker (Supervisor)

    1 Mar 20201 Aug 2020

    Activity: External examination and supervisionResearch degree

    Nanosystems for in-vivo self-assembling medical devices.

    Dipak Sarker (Presenter)

    14 Nov 201415 Nov 2014

    Activity: External talk or presentationInvited talk

    Cite this

    Kothur, R. R., Fucassi, F., Dichello, G., Doudet, L., Abdalaziz, W., Patel, B., Cave, G. W. V., Gass, I. A., Sarker, D., Mikhalovsky, S., & Cragg, P. (2015). Synthesis and applications of co-pillar[5]arene dithiols. Supramolecular Chemistry, 28(5-6), 436-443. https://doi.org/10.1080/10610278.2015.1111375