Structure and magnetism of new lanthanide 6-wheel compounds utilizing triethanolamine as a stabilizing ligand

Stuart K. Langley; Boujemaa Moubaraki; Craig M. Forsyth; Ian A. Gass; Keith S. Murray

doi:10.1039/b921843b

Structure and magnetism of new lanthanide 6-wheel compounds utilizing triethanolamine as a stabilizing ligand

Stuart K. Langley, Boujemaa Moubaraki, Craig M. Forsyth, Ian A. Gass, Keith S. Murray

University of Brighton

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of Ln(NO 3)3·6H2O (Ln = Gd, Dy) with triethanolamine (teaH3) and triethylamine in MeOH gives two isostructural hexanuclear wheels of formula [Ln6(teaH)6(NO3)6]·8MeOH, the magnetic properties of which show slow magnetisation relaxation in the Dy case.

Original language	English
Pages (from-to)	1705-1708
Number of pages	4
Journal	Dalton Transactions
Volume	39
Issue number	7
DOIs	https://doi.org/10.1039/b921843b
Publication status	Published - 23 Dec 2009

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title = "Structure and magnetism of new lanthanide 6-wheel compounds utilizing triethanolamine as a stabilizing ligand",

abstract = "The reaction of Ln(NO 3)3·6H2O (Ln = Gd, Dy) with triethanolamine (teaH3) and triethylamine in MeOH gives two isostructural hexanuclear wheels of formula [Ln6(teaH)6(NO3)6]·8MeOH, the magnetic properties of which show slow magnetisation relaxation in the Dy case.",

author = "Langley, {Stuart K.} and Boujemaa Moubaraki and Forsyth, {Craig M.} and Gass, {Ian A.} and Murray, {Keith S.}",

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T1 - Structure and magnetism of new lanthanide 6-wheel compounds utilizing triethanolamine as a stabilizing ligand

AU - Langley, Stuart K.

AU - Moubaraki, Boujemaa

AU - Forsyth, Craig M.

AU - Gass, Ian A.

AU - Murray, Keith S.

PY - 2009/12/23

Y1 - 2009/12/23

N2 - The reaction of Ln(NO 3)3·6H2O (Ln = Gd, Dy) with triethanolamine (teaH3) and triethylamine in MeOH gives two isostructural hexanuclear wheels of formula [Ln6(teaH)6(NO3)6]·8MeOH, the magnetic properties of which show slow magnetisation relaxation in the Dy case.

AB - The reaction of Ln(NO 3)3·6H2O (Ln = Gd, Dy) with triethanolamine (teaH3) and triethylamine in MeOH gives two isostructural hexanuclear wheels of formula [Ln6(teaH)6(NO3)6]·8MeOH, the magnetic properties of which show slow magnetisation relaxation in the Dy case.

U2 - 10.1039/b921843b

DO - 10.1039/b921843b

M3 - Article

SN - 1477-9226

VL - 39

SP - 1705

EP - 1708

JO - Dalton Transactions

JF - Dalton Transactions

IS - 7

ER -

Structure and magnetism of new lanthanide 6-wheel compounds utilizing triethanolamine as a stabilizing ligand

Abstract

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