Abstract
The complexes (N 4444)3[Ln(dcnm)6] (Ln=La–Nd, Sm; N4444= tetrabutylammonium) display a decrease in the melting point upon fast cooling from a melt, which is shown by in situ synchrotron based X-ray powder diffraction to be due to the formation of a second, less thermodynamically stable, polymorph.
Original language | English |
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Pages (from-to) | 124-126 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 48 |
Issue number | 1 |
DOIs | |
Publication status | Published - 3 Nov 2011 |