Graphene oxide-based degradation of metaldehyde: Effective oxidation through a modified Fenton’s process

Linh Viet Nguyen, Rosa Busquets Santacana, Santanu Ray, Andrew Cundy

Research output: Contribution to journalArticle

Abstract

A modified graphene oxide-based Fenton’s reaction has been investigated for the degradation of a challenging emerging contaminant which is not effectively removed in conventional water treatment. Metaldehyde, used as the challenge molecule in this study, is a common molluscicide that (like many highly soluble contaminants) has frequently breached European regulatory limits in surface waters. The new method involves graphene with higher hydrophilic characteristics (single-layer graphene oxide, SLGO) as a system that participates in a redox reaction with hydrogen peroxide and which can potentially stabilize theOH generated, which subsequently breaks down organic contaminants. The modified Fenton’s reaction has shown to be effective in degrading metaldehyde in natural waters (>92% removal), even at high contaminant concentrations (50mgmetaldehyde/L) and in the presence of high background organic matter and dissolved salts. The reaction is relatively pH insensitive. SLGO maintained its catalytic performance over 3 treatment cycles when immobilized. Its performance gradually decreased over time, reaching around 50% of starting performance on the 10th treatment cycle. X-ray photoelectron spectroscopy (XPS) analysis of modifications caused in SLGO by the oxidizing treatment indicated that the oxidation of CC sp2to carbonyl groups may be the cause of the decrease in performance. The proposed modified Fenton’s process has the potential to substitute traditional Fenton’s treatment although regeneration of the nanocarbon is required for its prolonged use.
Original languageEnglish
Pages (from-to)159-167
Number of pages9
JournalChemical Engineering Journal
Volume307
DOIs
Publication statusPublished - 12 Aug 2016

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Graphite
Oxides
Degradation
Oxidation
Impurities
Redox reactions
Water treatment
Surface waters
Biological materials
Hydrogen Peroxide
X ray photoelectron spectroscopy
Salts
metaldehyde
Molecules
Water

Bibliographical note

© 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/

Cite this

Nguyen, Linh Viet ; Busquets Santacana, Rosa ; Ray, Santanu ; Cundy, Andrew. / Graphene oxide-based degradation of metaldehyde: Effective oxidation through a modified Fenton’s process. In: Chemical Engineering Journal. 2016 ; Vol. 307. pp. 159-167.
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Graphene oxide-based degradation of metaldehyde: Effective oxidation through a modified Fenton’s process. / Nguyen, Linh Viet; Busquets Santacana, Rosa; Ray, Santanu; Cundy, Andrew.

In: Chemical Engineering Journal, Vol. 307, 12.08.2016, p. 159-167.

Research output: Contribution to journalArticle

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