Enantioselective Rh(I)-catalyzed cyclization of arylboron compounds onto ketones

Darryl W. Low; Graham Pattison; Martin D. Wieczysty; Gwydion H. Churchill; Hon Wai Lam

doi:10.1021/ol300845q

Enantioselective Rh(I)-catalyzed cyclization of arylboron compounds onto ketones

Darryl W. Low, Graham Pattison, Martin D. Wieczysty, Gwydion H. Churchill, Hon Wai Lam

Research output: Contribution to journal › Article › peer-review

Abstract

Rhodium complexes based upon chiral sulfinamide-alkene, TADDOL-derived phosphoramidite, or diene ligands catalyze cyclizations of arylboron compounds onto ketones, generating a variety of products containing five-, six-, or seven-membered rings with good yields and high enantioselectivities.

Original language	English
Pages (from-to)	2548-2551
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	10
DOIs	https://doi.org/10.1021/ol300845q
Publication status	Published - 18 May 2012

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title = "Enantioselective Rh(I)-catalyzed cyclization of arylboron compounds onto ketones",

abstract = "Rhodium complexes based upon chiral sulfinamide-alkene, TADDOL-derived phosphoramidite, or diene ligands catalyze cyclizations of arylboron compounds onto ketones, generating a variety of products containing five-, six-, or seven-membered rings with good yields and high enantioselectivities.",

author = "Low, {Darryl W.} and Graham Pattison and Wieczysty, {Martin D.} and Churchill, {Gwydion H.} and Lam, {Hon Wai}",

year = "2012",

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AU - Low, Darryl W.

AU - Pattison, Graham

AU - Wieczysty, Martin D.

AU - Churchill, Gwydion H.

AU - Lam, Hon Wai

PY - 2012/5/18

Y1 - 2012/5/18

N2 - Rhodium complexes based upon chiral sulfinamide-alkene, TADDOL-derived phosphoramidite, or diene ligands catalyze cyclizations of arylboron compounds onto ketones, generating a variety of products containing five-, six-, or seven-membered rings with good yields and high enantioselectivities.

AB - Rhodium complexes based upon chiral sulfinamide-alkene, TADDOL-derived phosphoramidite, or diene ligands catalyze cyclizations of arylboron compounds onto ketones, generating a variety of products containing five-, six-, or seven-membered rings with good yields and high enantioselectivities.

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U2 - 10.1021/ol300845q

DO - 10.1021/ol300845q

M3 - Article

C2 - 22540631

AN - SCOPUS:84862091090

SN - 1523-7060

VL - 14

SP - 2548

EP - 2551

JO - Organic Letters

JF - Organic Letters

IS - 10

ER -

Enantioselective Rh(I)-catalyzed cyclization of arylboron compounds onto ketones

Abstract

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