Enantioselective Rh(I)-catalyzed cyclization of arylboron compounds onto ketones

Darryl W. Low, Graham Pattison, Martin D. Wieczysty, Gwydion H. Churchill, Hon Wai Lam

Research output: Contribution to journalArticle

Abstract

Rhodium complexes based upon chiral sulfinamide-alkene, TADDOL-derived phosphoramidite, or diene ligands catalyze cyclizations of arylboron compounds onto ketones, generating a variety of products containing five-, six-, or seven-membered rings with good yields and high enantioselectivities.

Original languageEnglish
Pages (from-to)2548-2551
Number of pages4
JournalOrganic Letters
Volume14
Issue number10
DOIs
Publication statusPublished - 18 May 2012

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