Annelation of perfluorinated heteroaromatic systems by 1,3-dicarbonyl derivatives

Matthew W. Cartwright, Emma L. Parks, Graham Pattison, Rachel Slater, Graham Sandford, Ian Wilson, Dmitrii S. Yufit, Judith A.K. Howard, John A. Christopher, David D. Miller

Research output: Contribution to journalArticle

Abstract

Reactions of various perfluorinated heteroaromatic substrates such as tetrafluoro-4-cyanopyridine, tetrafluoropyrazine and tetrafluoropyridazine with 1,3-dicarbonyl systems gave corresponding [5,6]-ring fused furo derivatives. Subsequent reactions of the [5,6] bicyclic scaffolds with nucleophiles gave some highly functionalised heteroaromatic systems.

Original languageEnglish
Pages (from-to)3222-3227
Number of pages6
JournalTetrahedron
Volume66
Issue number17
DOIs
Publication statusPublished - 24 Apr 2010

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Nucleophiles
Scaffolds
Derivatives
Substrates
4-cyanopyridine

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Cartwright, M. W., Parks, E. L., Pattison, G., Slater, R., Sandford, G., Wilson, I., ... Miller, D. D. (2010). Annelation of perfluorinated heteroaromatic systems by 1,3-dicarbonyl derivatives. Tetrahedron, 66(17), 3222-3227. https://doi.org/10.1016/j.tet.2010.02.083
Cartwright, Matthew W. ; Parks, Emma L. ; Pattison, Graham ; Slater, Rachel ; Sandford, Graham ; Wilson, Ian ; Yufit, Dmitrii S. ; Howard, Judith A.K. ; Christopher, John A. ; Miller, David D. / Annelation of perfluorinated heteroaromatic systems by 1,3-dicarbonyl derivatives. In: Tetrahedron. 2010 ; Vol. 66, No. 17. pp. 3222-3227.
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Cartwright, MW, Parks, EL, Pattison, G, Slater, R, Sandford, G, Wilson, I, Yufit, DS, Howard, JAK, Christopher, JA & Miller, DD 2010, 'Annelation of perfluorinated heteroaromatic systems by 1,3-dicarbonyl derivatives', Tetrahedron, vol. 66, no. 17, pp. 3222-3227. https://doi.org/10.1016/j.tet.2010.02.083

Annelation of perfluorinated heteroaromatic systems by 1,3-dicarbonyl derivatives. / Cartwright, Matthew W.; Parks, Emma L.; Pattison, Graham; Slater, Rachel; Sandford, Graham; Wilson, Ian; Yufit, Dmitrii S.; Howard, Judith A.K.; Christopher, John A.; Miller, David D.

In: Tetrahedron, Vol. 66, No. 17, 24.04.2010, p. 3222-3227.

Research output: Contribution to journalArticle

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AU - Cartwright, Matthew W.

AU - Parks, Emma L.

AU - Pattison, Graham

AU - Slater, Rachel

AU - Sandford, Graham

AU - Wilson, Ian

AU - Yufit, Dmitrii S.

AU - Howard, Judith A.K.

AU - Christopher, John A.

AU - Miller, David D.

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AB - Reactions of various perfluorinated heteroaromatic substrates such as tetrafluoro-4-cyanopyridine, tetrafluoropyrazine and tetrafluoropyridazine with 1,3-dicarbonyl systems gave corresponding [5,6]-ring fused furo derivatives. Subsequent reactions of the [5,6] bicyclic scaffolds with nucleophiles gave some highly functionalised heteroaromatic systems.

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Cartwright MW, Parks EL, Pattison G, Slater R, Sandford G, Wilson I et al. Annelation of perfluorinated heteroaromatic systems by 1,3-dicarbonyl derivatives. Tetrahedron. 2010 Apr 24;66(17):3222-3227. https://doi.org/10.1016/j.tet.2010.02.083