Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

David J. Harding; Wasinee Phonsri; Phimphaka Harding; Ian A. Gass; Keith S. Murray; Boujemaa Moubaraki; John D. Cashion; Lujia Liu; Shane G. Telfer

doi:10.1039/c3cc42125b

Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

David J. Harding
, Wasinee Phonsri
, Phimphaka Harding
, Ian A. Gass
, Keith S. Murray
, Boujemaa Moubaraki
, John D. Cashion
, Lujia Liu
, Shane G. Telfer

University of Brighton

Research output: Contribution to journal › Article › peer-review

Abstract

The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.

Original language	English
Pages (from-to)	6340-6342
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	56
DOIs	https://doi.org/10.1039/c3cc42125b
Publication status	Published - 4 Jun 2013

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title = "Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects",

abstract = "The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.",

author = "Harding, \{David J.\} and Wasinee Phonsri and Phimphaka Harding and Gass, \{Ian A.\} and Murray, \{Keith S.\} and Boujemaa Moubaraki and Cashion, \{John D.\} and Lujia Liu and Telfer, \{Shane G.\}",

year = "2013",

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doi = "10.1039/c3cc42125b",

language = "English",

volume = "49",

pages = "6340--6342",

journal = "Chemical Communications",

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T1 - Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

AU - Harding, David J.

AU - Phonsri, Wasinee

AU - Harding, Phimphaka

AU - Gass, Ian A.

AU - Murray, Keith S.

AU - Moubaraki, Boujemaa

AU - Cashion, John D.

AU - Liu, Lujia

AU - Telfer, Shane G.

PY - 2013/6/4

Y1 - 2013/6/4

N2 - The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.

AB - The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.

U2 - 10.1039/c3cc42125b

DO - 10.1039/c3cc42125b

M3 - Article

SN - 1359-7345

VL - 49

SP - 6340

EP - 6342

JO - Chemical Communications

JF - Chemical Communications

IS - 56

ER -

Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

Abstract

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