Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

David J. Harding, Wasinee Phonsri, Phimphaka Harding, Ian A. Gass, Keith S. Murray, Boujemaa Moubaraki, John D. Cashion, Lujia Liu, Shane G. Telfer

Research output: Contribution to journalArticle

Abstract

The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.
Original languageEnglish
Pages (from-to)6340-6342
Number of pages3
JournalChemical Communications
Volume49
Issue number56
DOIs
Publication statusPublished - 4 Jun 2013

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