Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

David J. Harding; Wasinee Phonsri; Phimphaka Harding; Ian A. Gass; Keith S. Murray; Boujemaa Moubaraki; John D. Cashion; Lujia Liu; Shane G. Telfer

doi:10.1039/c3cc42125b

Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

David J. Harding, Wasinee Phonsri, Phimphaka Harding, Ian A. Gass, Keith S. Murray, Boujemaa Moubaraki, John D. Cashion, Lujia Liu, Shane G. Telfer

University of Brighton

Research output: Contribution to journal › Article › peer-review

Abstract

The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.

Original language	English
Pages (from-to)	6340-6342
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	56
DOIs	https://doi.org/10.1039/c3cc42125b
Publication status	Published - 4 Jun 2013

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title = "Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects",

abstract = "The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.",

author = "Harding, {David J.} and Wasinee Phonsri and Phimphaka Harding and Gass, {Ian A.} and Murray, {Keith S.} and Boujemaa Moubaraki and Cashion, {John D.} and Lujia Liu and Telfer, {Shane G.}",

year = "2013",

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doi = "10.1039/c3cc42125b",

language = "English",

volume = "49",

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T1 - Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

AU - Harding, David J.

AU - Phonsri, Wasinee

AU - Harding, Phimphaka

AU - Gass, Ian A.

AU - Murray, Keith S.

AU - Moubaraki, Boujemaa

AU - Cashion, John D.

AU - Liu, Lujia

AU - Telfer, Shane G.

PY - 2013/6/4

Y1 - 2013/6/4

N2 - The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.

AB - The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.

U2 - 10.1039/c3cc42125b

DO - 10.1039/c3cc42125b

M3 - Article

SN - 1359-7345

VL - 49

SP - 6340

EP - 6342

JO - Chemical Communications

JF - Chemical Communications

IS - 56

ER -

Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

Abstract

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