A Cube in a Tetrahedron: Microwave-Assisted Synthesis of an Octametallic Fe III Cluster

Ian A. Gass; Constantinos J. Milios; A. Gavin Whittaker; Fransesca P.A. Fabiani; Simon Parsons; Mark Murrie; Spyros P. Perlepes; Euan K. Brechin

doi:10.1021/ic0607843

A Cube in a Tetrahedron: Microwave-Assisted Synthesis of an Octametallic Fe III Cluster

Ian A. Gass, Constantinos J. Milios, A. Gavin Whittaker, Fransesca P.A. Fabiani, Simon Parsons, Mark Murrie, Spyros P. Perlepes, Euan K. Brechin

University of Brighton

Research output: Contribution to journal › Article › peer-review

Abstract

The microwave-assisted reaction of Fe(O 2CMe)2 with salicylaldoxime (saoH2) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao2- exhibits a novel coordination mode.

Original language	English
Pages (from-to)	5281-5283
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	14
DOIs	https://doi.org/10.1021/ic0607843
Publication status	Published - 6 Oct 2006

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title = "A Cube in a Tetrahedron: Microwave-Assisted Synthesis of an Octametallic Fe III Cluster",

abstract = "The microwave-assisted reaction of Fe(O 2CMe)2 with salicylaldoxime (saoH2) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao2- exhibits a novel coordination mode.",

author = "Gass, \{Ian A.\} and Milios, \{Constantinos J.\} and Whittaker, \{A. Gavin\} and Fabiani, \{Fransesca P.A.\} and Simon Parsons and Mark Murrie and Perlepes, \{Spyros P.\} and Brechin, \{Euan K.\}",

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AU - Gass, Ian A.

AU - Milios, Constantinos J.

AU - Whittaker, A. Gavin

AU - Fabiani, Fransesca P.A.

AU - Parsons, Simon

AU - Murrie, Mark

AU - Perlepes, Spyros P.

AU - Brechin, Euan K.

PY - 2006/10/6

Y1 - 2006/10/6

N2 - The microwave-assisted reaction of Fe(O 2CMe)2 with salicylaldoxime (saoH2) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao2- exhibits a novel coordination mode.

AB - The microwave-assisted reaction of Fe(O 2CMe)2 with salicylaldoxime (saoH2) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao2- exhibits a novel coordination mode.

U2 - 10.1021/ic0607843

DO - 10.1021/ic0607843

M3 - Article

SN - 0020-1669

VL - 45

SP - 5281

EP - 5283

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 14

ER -

A Cube in a Tetrahedron: Microwave-Assisted Synthesis of an Octametallic Fe III Cluster

Abstract

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