A Cube in a Tetrahedron: Microwave-Assisted Synthesis of an Octametallic Fe III Cluster

Ian A. Gass; Constantinos J. Milios; A. Gavin Whittaker; Fransesca P.A. Fabiani; Simon Parsons; Mark Murrie; Spyros P. Perlepes; Euan K. Brechin

doi:10.1021/ic0607843

A Cube in a Tetrahedron: Microwave-Assisted Synthesis of an Octametallic Fe III Cluster

Ian A. Gass
, Constantinos J. Milios
, A. Gavin Whittaker
, Fransesca P.A. Fabiani
, Simon Parsons
, Mark Murrie
, Spyros P. Perlepes
, Euan K. Brechin

University of Brighton

Research output: Contribution to journal › Article › peer-review

Abstract

The microwave-assisted reaction of Fe(O 2CMe)2 with salicylaldoxime (saoH2) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao2- exhibits a novel coordination mode.

Original language	English
Pages (from-to)	5281-5283
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	14
DOIs	https://doi.org/10.1021/ic0607843
Publication status	Published - 6 Oct 2006

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title = "A Cube in a Tetrahedron: Microwave-Assisted Synthesis of an Octametallic Fe III Cluster",

abstract = "The microwave-assisted reaction of Fe(O 2CMe)2 with salicylaldoxime (saoH2) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao2- exhibits a novel coordination mode.",

author = "Gass, \{Ian A.\} and Milios, \{Constantinos J.\} and Whittaker, \{A. Gavin\} and Fabiani, \{Fransesca P.A.\} and Simon Parsons and Mark Murrie and Perlepes, \{Spyros P.\} and Brechin, \{Euan K.\}",

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AU - Gass, Ian A.

AU - Milios, Constantinos J.

AU - Whittaker, A. Gavin

AU - Fabiani, Fransesca P.A.

AU - Parsons, Simon

AU - Murrie, Mark

AU - Perlepes, Spyros P.

AU - Brechin, Euan K.

PY - 2006/10/6

Y1 - 2006/10/6

N2 - The microwave-assisted reaction of Fe(O 2CMe)2 with salicylaldoxime (saoH2) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao2- exhibits a novel coordination mode.

AB - The microwave-assisted reaction of Fe(O 2CMe)2 with salicylaldoxime (saoH2) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao2- exhibits a novel coordination mode.

U2 - 10.1021/ic0607843

DO - 10.1021/ic0607843

M3 - Article

SN - 0020-1669

VL - 45

SP - 5281

EP - 5283

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 14

ER -

A Cube in a Tetrahedron: Microwave-Assisted Synthesis of an Octametallic Fe III Cluster

Abstract

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