A Coupling Approach for the Generation of α,α-Bis(enolate) Equivalents: Regioselective Synthesis of gem-Difunctionalized Ketones

Keyphrases

• Alkyl Halides 33%
• Boron Compounds 33%
• Coupling Approach 100%
• Difunctionalization 33%
• Electrophile 33%
• Enolates 100%
• Esters 33%
• Fluorinating Agent 33%
• Geminal 33%
• Ketones 100%
• Metal-free Coupling 33%
• Regioselective Synthesis 100%
• Regioselectivity 33%
• Synthetic Strategies 33%
• Transition-metal-free 33%
• Unsymmetrical 33%

Chemistry

• Boron Compound 50%
• Electrophile 50%
• Enolates 100%
• Halide 50%
• Ketone 50%
• Ketones 100%
• Transition Metal 50%